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SELECT 
  1 
FROM 
  cscart_multi_declock_keys 
WHERE 
  key_id = '5121a4f8d0875e313b47b47ee5e3a9580aabe191ab3802027e4541506a323d94' 
  AND token = 'NGPpZrLbl+Liy7tHbelKarG6oMzLrDXwlBFRt3fLpc8=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00028

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}