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SELECT 
  1 
FROM 
  cscart_multi_declock_keys 
WHERE 
  key_id = '00c95414e7991846d9789288d3fc40a402f65ce72e6c364b239fbda23e36670e' 
  AND token = 'LN8aTAnw2k86pbkIFLJvu8HNjiAudaMLYHzRBRqfB+A=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00019

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}