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SELECT 
  1 
FROM 
  cscart_multi_declock_keys 
WHERE 
  key_id = 'af1c514363898163e2270d099f831671b12da2200daf4e9590eae70a43f5dc55' 
  AND token = '9/gCese0e8kexYuP+2C1jLUyyUsHjStzdeZr5kx6awA=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00022

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}