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SELECT 
  1 
FROM 
  cscart_aprillock_keys 
WHERE 
  key_id = '31512de0bb2ce6f990346c9bdc76552b42dd50e77e940890d8beeda29a389b42' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00037

JSON explain

{
  "query_block": {
    "select_id": 1,
    "message": "no matching row in const table"
  }
}